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due to ortho effect okk but
it is exception
4,2,1,3
it is exception
4,2,1,3
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akshara38:
uu
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The first one is highly acidic owing to Ortho effect.
Then comes the second one (amido group at meta) because it operates -I effect.
Then comes the last one. Its comparatively more acidic than the third one (amido group at para) since the group operates +R effect which makes it the least acidic.
And we know that -I,-R effects increases acidity whereas +I,+R effect decreases acidity.
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