postulates of werners theory
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Postulates of Werner's Theory. The important postulates of Werner's theory are: The central metal or the metal atoms in coordination compounds show two types of valency. ... On the other hand, a negative ion or neutral molecules satisfy secondary valencies.
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( a ) A metal shows two kinds of valencies viz primary valency and secondary valency.Negative ionssatisfy primary valenciesand secondaryvalencies are filled by bothneutral ions and negative ions.
( b ) A metal ion has a fixed amount of secondary valencies about the central atom. These valenciesalso orient themselves in a particular direction in the space provided to the definite geometry of the coordination compound.
( c ) Secondary valencies cannot be ionized , while primary valencies can usually be ionized.
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