Chemistry, asked by ni200251, 1 year ago

prove that ∆H=∆U+∆nRT what is condition under which ∆u=∆H​

Answers

Answered by Lamesoul
28

Answer :

This equation shows the Change in enthalpy.

∆H=∆U+∆nRT

proof

Pv = nRT

so let us consider that ,

vA = nA

and

vB = nB.

so we get,

p(vB - vA) = (nB - nA) RT

So ,

P∆V = ngRT

∆H=∆U +p∆v

Proved !!

condition : ∆u=∆H

at constant temperature

T = 0

now let's put the value of T equal to zero in the above equation :

and we get the following results.

∆H=∆U+∆nRT

(putting the value of T = 0 )

∆H=∆U

reason:

under isothermal condition value of temperature becomes constant so in order to make change in enthalpy equal to change in internal energy an isothermal condition should be created.

Answered by cutepgl
12

Answer:

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may it helps you

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