Chemistry, asked by shabirs2081, 10 months ago

Prove that the radius of nth bohr's orbit of an atom is directly proportional to n2

Answers

Answered by Lipsa133
2

Explanation:

here the formula for radius is directly proportional to n^2

Attachments:
Answered by fistshelter
3

Yes, radius of nth orbit of hydrogen atom is directly proportional to n^2 as :---

As per Coulomb's law:

F = \frac{q_{1} q_{2}}{4\pi \epsilon r^{2}}

\frac{1}{4\pi \epsilon } = 9 x 10^{9} (in MKS)

     = 1          (in CGS)

Force of attraction betwween electron and nucleus

F = \frac{K z e^{2} }{r^{2} }

Centrifugal force balances electrostatic force

\frac{mv^{2} }{r} =  \frac{K z e^{2} }{r^{2} }          

mv^{2} = \frac{Kze^{2} }{r}               ....(I)

But according to Bohr

mvr = \frac{nh}{2\pi }

v = \frac{nh}{2\pi r}

v^{2} = \frac{n^{2}h^{2}  }{4\pi ^{2} m^{2} r^{2} }

Putting value in (i)

\frac{m n^{2}h^{2}  }{4\pi ^{2} m^{2} r^{2} } = \frac{Kze^{2} }{r}

r = \frac{n^{2}h^{2}  }{4\pi ^{2} m Kze^{2}  }

r = \frac{0.529 n^{2} }{Z} angstrom

Radius of first shell of Hydrogen is 0.529 angstrom

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