ques69
69. The two isomer x and y with the formula Cr(H2O)5ClBr2 were taken for experiment on depression in freezing point.It was found that 1 mol of 'x' gave depression corresponding to 2 mole of particles and 1 mole of 'y' gave depression due to 3 mole of particles.The structural formulae of x and y respectively are:-
(1) [Cr(H2O)5Cl]Br2;[Cr(H2O)4Br2]Cl.H2O(2) [Cr(H2O)5Cl]Br2;[Cr(H2O)3ClBr2]2.H2O(3) [Cr(H2O)5Br]BrCl;[Cr(H2O)4ClBr]Br.H2O(4) [Cr(H2O)4Br2]Cl.H2O;[Cr(H2O)5Cl]Br2
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