Question 12.15 What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?
(a)
(b)
(c)
Class XI Organic Chemistry : Some Basic Principles and Techniques Page 362
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(a) Here, we can see that position of the functional group (ketones ) are different .hence , it is structural isomers.
(b) DHC=CHD ; trans isomer
similar group are in opposite side of double bond is known as trans isomer.
DHC=CDH; cis - isomer
similar group are in same side of double bond is known as cis - isomer.
you know, Cis/trans isomer is in Geometrical isomer . hence, it is Geometrical isomer.
(c) here, we see the position of electron is defference but position of atoms are same. hence,it is example of resonance contributor
(b) DHC=CHD ; trans isomer
similar group are in opposite side of double bond is known as trans isomer.
DHC=CDH; cis - isomer
similar group are in same side of double bond is known as cis - isomer.
you know, Cis/trans isomer is in Geometrical isomer . hence, it is Geometrical isomer.
(c) here, we see the position of electron is defference but position of atoms are same. hence,it is example of resonance contributor
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