Real gases deviate from ideal behaviour.Is this statement true.Give reason
Answers
Answer:
Real Gases Do Not Obey the Ideal Gas Law, Especially at High Pressures. (a) In these plots of PV/nRT versus P at 273 K for several common gases, there are large negative deviations observed for C2H4 and CO2 because they liquefy at relatively low pressures. ... 2: The Effect of Temperature on the Behavior of Real Gases.
Explanation:
Van der Waals Equation
The behavior of real gases usually agrees with the predictions of the ideal gas equation to within 5% at normal temperatures and pressures. At low temperatures or high pressures, real gases deviate significantly from ideal gas behavior. In 1873, while searching for a way to link the behavior of liquids and gases, the Dutch physicist Johannes van der Waals developed an explanation for these deviations and an equation that was able to fit the behavior of real gases over a much wider range of pressures.
Van der Waals realized that two of the assumptions of the kinetic molecular theory were questionable. The kinetic theory assumes that gas particles occupy a negligible fraction of the total volume of the gas. It also assumes that the force of attraction between gas molecules is zero.
The first assumption works at pressures close to 1 atm. But something happens to the validity of this assumption as the gas is compressed. Imagine for the moment that the atoms or molecules in a gas were all clustered in one corner of a cylinder, as shown in the figure below. At normal pressures, the volume occupied by these particles is a negligibly small fraction of the total volume of the gas. But at high pressures, this is no longer true. As a result, real gases are not as compressible at high pressures as an ideal gas. The volume of a real gas is therefore larger than expected from the ideal gas equation at high pressures.
Van der Waals proposed that we correct for the fact that the volume of a real gas is too large at high pressures by subtracting a term from the volume of the real gas before we substitute it into the ideal gas equation. He therefore introduced a constant
constant (b) into the ideal gas equation that was equal to the volume actually occupied by a mole of gas particles. Because the volume of the gas particles depends on the number of moles of gas in the container, the term that is subtracted from the real volume of the gas is equal to the number of moles of gas times b.
P(V - nb) = nRT
When the pressure is relatively small, and the volume is reasonably large, the nb term is too small to make any difference in the calculation. But at high pressures, when the volume of the gas is small, the nb term corrects for the fact that the volume of a real gas is larger than expected from the ideal gas equation.
The assumption that there is no force of attraction between gas particles cannot be true. If it was, gases would never condense to form liquids. In reality, there is a small force of attraction between gas molecules that tends to hold the molecules together. This force of attraction has two consequences: (1) gases condense to form liquids at low temperatures and (2) the pressure of a real gas is sometimes smaller than expected for an ideal gas.
To correct for the fact that the pressure of a real gas is smaller than expected from the ideal gas equation, van der Waals added a term to the pressure in this equation. This term contained a second constant (a) and has the form: an2/V2. The complete van der Waals equation is therefore written as follows.
This equation is something of a mixed blessing. It provides a much better fit with the behavior of a real gas than the ideal gas equation. But it does this at the cost of a loss in generality. The ideal gas equation is equally valid for any gas, whereas the van der Waals equation contains a pair of constants (a and b) that change from gas to gas.
The ideal gas equation predicts that a plot of PV versus P for a gas would be a horizontal line because PV should be a constant. Experimental data for PV versus P for H2 and N2 gas at 0�C and CO2 at 40C are given in the figure below. Values of the van der Waals constants for these and other gases are given in the table below.
van der Waals Constants for Various Gases
Compound a (L2-atm/mol2) b (L/mol)
He 0.03412 0.02370
Ne 0.2107 0.01709
H2 0.2444 0.02661
Ar 1.345 0.03219
O2 1.360 0.03803
N2 1.390 0.03913
CO 1.485 0.03985
CH4 2.253 0.04278
CO2 3.592 0.04267
NH3 4.170 0.03707
The magnitude of the deviations from ideal gas behavior can be illustrated by comparing the results of calculations using the ideal gas equation and the van der Waals equation for 1.00 mole of CO2 at 0oC in containers of different volumes. Let's start with a 22.4 L container.
According to the ideal gas equation, the pressure of this gas should be 1.00 atm.
Substituting what we know about CO2 into the van der Waals equation gives a much more complex equation.