Select the correct statement (s) 1) Polarizability of S²‾ is lower than Se²‾ 2) Polarizability of S²‾ is higher than Cl ‾ 3) Polarizability of S²‾ is lower than P3‾ 4) Polarizability of O²‾ is higher than S2‾
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2) Polarizability of S²‾ is higher than
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The correct statements are options 1, 2, and 3.
- Despite the fact that the magnitude of charge for both the Sulphur ion (S²‾) and the Selenium ion (Se²‾) is the same, Se²‾ is larger than S²‾.
- Hence, the polarizability of an anion increases with its size, Se²‾ is more polarizable than S²‾ and the option (1) is correct.
- Among S²‾ and chlorine ion (Cl‾ ) which have the same magnitude of charge, S²‾ is more polarizable since it is larger in size than Cl ‾.
- The size and the magnitude of the negative charge of Phosphorus ion (P³‾) is more than S²‾ and hence it is more polarizable.
- The polarizability of an anion is directly proportional to its magnitude of negative charge.
- Among Oxygen ion (O²‾) and S²‾ which have the same magnitude of charge, S²‾ is more polarizable since it is larger in size than O²‾. Hence, option (4) is not valid.
- Polarizability is the tendency of molecules to produce induced electric dipole moments when exposed to an electric field.
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