Standard entropies of X2, Y2 and XY3 are 60,40 and 50JK–1mol–1 respectively. For the reaction 12X2+32Y2⇋XY3,ΔH=−30kJ to be at 2 equilibrium, the temperature should be:
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Answered by
58
Answer:
The correct option is : (a) 750 K
Explanation:
Given reaction is :
1/2 X₂ + 3/2 Y₂⇄XY₃
we know,
ΔS°=∑S°products - ∑S°reactant
=50 - (30+60)
=-40 J K^-1 mol^-1
at equilibrium ΔG° = 0
ΔH° = TΔS°
∴T = ΔH°/ΔS°
T = -30 × 10³ J mol^-1 / -40 J K^-1 mol^-1
∴T = 750 K
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