steric effects of inert ligands Nucleophilic reactivity?send me google link
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“inert” complexes have t1/2 > 1 min. ... Steric crowding slows down the reaction: Evidence for an associative mechanism. ... The trans effect is best defined as the effect of a coordinated lignd upon the.
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Steric effects are nonbonding interactions that influence the shape (conformation) and reactivity of ions and molecules. Steric effects complement electronic effects, which dictate the shape and reactivity of molecules. Steric repulsive forces between overlapping electron clouds result in structured groupings of molecules stabilized by the way that opposites attract and like charges repel.
The parent cyclobutadiene (R = H) readily dimerizes but the R = tert-butyl derivative is robust.[1]
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