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Answer:
Correct option is
A
−226 and +467
N
2
+3X
2
→2NX
3
Energy to break 1 mole of N
2
bond =941 kJmol
−1
Energy to break 3 mole of F
2
bond =3×155 kJ mol
−1
Energy released caused of bond formation of 2 moles of 3 bonds N−F=2×3×272
Heat of formation of NF
3
by Hess law =941+3×155−(2×3×272)=−226 kJ mol
−1
Similarly for NCl
3
,
Just replacing the necessary values in previous calculations, heat of formation of NCl
3
=941+3×242−(2×3×200)=+467 kJmol
−1
.
Hence, option A is correct.
Step-by-step explanation:
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