→ Explain why chlorination is more reactive than bromination
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Chlorination is less selective than bromination because chlorination has smaller differences in activation energy for attack at 1°, 2°, and 3° positions. Consider the halogenation of propane at the 1° and 2° positions. Formation of the different halopropanes occurs during the chain propagation steps.
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This is because chlorination forms a strong H-Cl bond (103 kcal/mol) and bromination forms a much weaker H-Br bond (87 kcal/mol). ... In bromination, the reaction is endothermic, and the transition state resembles the products.O
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