Cp-Cv= R
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For an ideal gas, internal energy(U) and enthalpy(H) are functions of temperature(T) only , due to the ASSUMPTION of very low inter molecular forces between atoms/molecules . Therefore, specific heats at constant volume and pressure may be defined as follows, without resorting to partial derivatives.
C(v) =dU/dT…………..…………(1)
C(p)=dH/dT……………………..(2)
H=U+PV…………………………..(3)
PV=RT (ideal gas law)………..(4)
Differentiating (3)&(4) wrt temperature and substituting (1)&(2)we get,
dH/dT=dU/dT +d(PV)/dT
C(p)=C(v)+R
C(p)-C(v)=R
Explanation:
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