The boiling point of water is 100
c. Calculate thr boiling point of an aqueous solution containing 0.6 g of urea in 100 kg of water
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Explanation:
from elevation in boiling,
=kb.m
where \Delta T_bΔT
b
is elevation in boiling point, K_bK
b
is ebullioscopic constant and m is molality of solute.
mass of urea = 0.6 g
molar mass of urea (solute) = 60g/mol
so, number of mole of urea = 0.6/60 = 0.01
mass of solvent (water) = 100g
so, molality of urea = number of mole of urea/mass of solvent in kg
= 0.01 × 1000/100 = 0.1 molal
given, ebullioscopic constant, K_bK
b
= 0.52K/molal or 0.52°C/molal
then, ∆Tb = 0.52 × 0.1 = 0.052K
so, boiling point of solution, Tb = T + 0.052°C
= 100°C + 0.052 °C = 100.052°C
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