The % composition of a substance is P =32.63 , 0 =16.82 & S = 50.55. The V.D of substance is 190. Find the molecular formula of the substance .
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Find the ratio between the molar mass and the percentage of each element
P = \frac{32.63}{31}
31
32.63
= 1
O = \frac{16.82}{16}
16
16.82
= 1
S = \frac{50.55}{32}
32
50.55
= 1.5
By taking ratio: 1: 1: 1.5 = 2: 2: 3
So, the empirical formula will be: P₂O₂S₃
Molar mass of P₂O₂S₃ = 190
Molar mass of a compound = 2 x V.D
= 2 x 190 = 380
divide 380 by 190
You will get 2
Now, multiply the number of atoms in P₂O₂S₃ by 2
=> P₄O₄S₆ is your answer
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