Chemistry, asked by ananditamahani5026, 10 months ago

The correct bond order in the following species is: [2015]
(a) O₂²⁺ < O₂⁻ < O₂⁺ (b) O₂⁺ < O₂⁻ < O₂²⁺
(c) O₂⁻ < O₂⁺ < O₂²⁺ (d) O₂²⁺ < O₂⁺ < O₂⁻

Answers

Answered by maanik8
2

Answer:

Options c Should ne corrected

Explanation:

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Answered by rishikeshm1912
1

The correct bond order of given species is O₂⁻ < O₂⁺ < O₂²⁺

Explanation:

Electronic configurations and bond order of the given species are

O_2^{-} - \sigma1s^2,\sigma^{*}1s^2,\sigma2s^2,\sigma^{*}2s^2,\sigma2p_x^2,\pi2p_y^2=\pi2p_z^2,\pi^{*}2p_y^2=\pi^{*}2p_z^1

Bond \,order=\frac{N_b-N_a}{2} =\frac{10-7}{2} =1.5

O_2^{+} - \sigma1s^2,\sigma^{*}1s^2,\sigma2s^2,\sigma^{*}2s^2,\sigma2p_x^2,\pi2p_y^2=\pi2p_z^2,\pi^{*}2p_y^1=\pi^{*}2p_z^0

Bond \,order=\frac{N_b-N_a}{2} =\frac{10-5}{2} =2.5

O_2^{2+} - \sigma1s^2,\sigma^{*}1s^2,\sigma2s^2,\sigma^{*}2s^2,\sigma2p_x^2,\pi2p_y^2=\pi2p_z^2

Bond \,order=\frac{N_b-N_a}{2} =\frac{10-6}{2} =3

\therefore The correct bond order is O₂⁻ < O₂⁺ < O₂²⁺

Hence the correct answer is option c

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