the correct order of equivalent conductance at infinite dilution of LiCl NaCl and KCL
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108
the correct order is KCl > NaCl > LiCl .
explanation:- in case of Alkali metals , hydration energy decreases with increase atomic number e.g., order of hydration energy is Li+ > Na+ > K+ > Rb+ > Cs+ .
and we know, mobility is inversely proportional to hydration energy so,
order of mobility is Cs+ > Rb+ > K+ > Na+ > Li+
now, equivalent conductance is directly proportional to mobility .
that's why order of equivalent conductance is K+ > Na+ > Li+
hence, order of equivalent conductance is KCl > NaCl > LiCl
explanation:- in case of Alkali metals , hydration energy decreases with increase atomic number e.g., order of hydration energy is Li+ > Na+ > K+ > Rb+ > Cs+ .
and we know, mobility is inversely proportional to hydration energy so,
order of mobility is Cs+ > Rb+ > K+ > Na+ > Li+
now, equivalent conductance is directly proportional to mobility .
that's why order of equivalent conductance is K+ > Na+ > Li+
hence, order of equivalent conductance is KCl > NaCl > LiCl
Answered by
42
The correct Order of equivalent Conductance at infinite dilution of LiCl, NaCl and KCl is :
KCl>NaCl>LiCl
Reason:
In case of Alkali metals ions like Sodium, Lithium and potassium the hydration tendency follows the order
Li+>Na+>K+
Hydration makes the cation heavier and larger
Hence mobility has the following order :Li+<Na+< K+
HenceThe correct Order of equivalent Conductance at infinite dilution of LiCl, NaCl and KCl is :
KCl>NaCl>LiCl
KCl>NaCl>LiCl
Reason:
In case of Alkali metals ions like Sodium, Lithium and potassium the hydration tendency follows the order
Li+>Na+>K+
Hydration makes the cation heavier and larger
Hence mobility has the following order :Li+<Na+< K+
HenceThe correct Order of equivalent Conductance at infinite dilution of LiCl, NaCl and KCl is :
KCl>NaCl>LiCl
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