The correct order of ionisation enthalpy of boron family
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Ionization Energy
Down the group, the values of Ionization Enthalpy do not decrease smoothly. From Boron to Aluminium, the Ionization Enthalpy increase as expected. But from Aluminium to Gallium, the Ionization Enthalpy increase slightly. The first Ionization Enthalpy of Thallium is greater than Aluminium.
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