Chemistry, asked by maysmithjames2339, 1 year ago

The de-broglie's wavelength of electron present in first bohr orbit of ‘h' atom is

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Answered by bapu34
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Answered by zumba12
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The De-broglie's wavelength of electron present in first Bohr orbit of ‘h' atom is 2\pi\times0.529A^0.

Given:

  • Electron present in first Bohr orbit of 'H' atoms.

To find:

  • De-broglie's wavelength of electron = ?

Calculation:

We know that in the Bohr model, the angular momentum is given as follows:

mvr=\frac{nh}{2\times\pi} ................. (1)

where:

m- mass

v - Velocity

r - Radius

n - Orbital state

h - Plank's constant

Momentum 'P' is product of mass and velocity and its formula is

P = \frac{h}{\lambda}

Substituting the value of 'P' in equation (1) gives:

mvr=\frac{nh}{2\times\pi}

Pr=\frac{nh}{2\times\pi}        (∵ mv = p)

\frac{h}{\lambda}\times r = \frac{nh}{2\times\pi}     (∵ P = \frac{h}{\lambda})

As 'h' is common in both side it gets cancelled and the equation becomes

\frac{r}{\lambda} = \frac{n}{2\pi}

On cross multiplication it gives

\lambda\times n=r\times2\pi

As we required to find wavelength, the formula must be altered as shown:

\lambda = \frac{r\times2\pi}{n}

Now substituting the required values gives the de-broglie's wavelength:

The standard radius (r) value for hydrogen atom is 0.529A^0, and value of n is 1.

\lambda = \frac{r\times2\pi}{n}

\lambda = \frac{0.529\times2\pi}{1}

\lambda = 0.529\times2\pi

\lambda = 2\pi\times0.529

Conclusion:

Thus the de-broglie's wavelength of electron present in first Bohr orbit of ‘h' atom is calculated as 2\pi\times0.529A^0.

Learn more about such concept

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