The dissociation constant of two acids HA₁ and HA₂ are
3.14 × 10⁻⁴ and 1.96 × 10⁻⁵ respectively. The relative strength
of the acids will be approximately
(a) 1 : 4 (b) 4 : 1
(c) 1 : 16 (d) 16 : 1
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The relative strength of the acids will be approximately 4 : 1
Option (B) is correct.
Explanation:
- The dissociation constants of HA1 and HA2 are 3 x 10^-4 and 1.8 x 10^-5
- The strength of an acid is directly proportional to square root of dissociation constants of acids.
- So relative strength of the given acids are:
- Relative Acidic Strength = (Acidic Strength) HA2 /(Acidic Strength) HA1
- Relative Acidic Strength = √ 3 x 10^-4 / √ 1.8 x 10^-5 = 4.08 = 4
Thus the relative strength of the acids will be approximately 4 : 1
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