the enthalpy change for the reaction H2O (l) = H2O (g) is called enthalpy of
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Let's put it this way:
H2(g)+1/2O2(g)→H2O(g)
H2(g)+1/2O2(g)→H2O(l)
Although the reactants of the reactions are the same, pay attention to the products. H2O(g) and H2O(l) are different.
H2O(g)→H2O(l)
This reaction is exothermic, causing that H2O(l) is more stable than H2O(g). That is, std. enthalpy of formation for H2O(l)(-285.8kJ/mol) is smaller than that for H2O(g)(-241.82kJ/mol).
In a word, the different phase of substances do matter when talking about std. enthalpy of formation.
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