The ∆fH° for CO2(g) ; CO(g) and H2O (g) are -393.5, -110.5 and -241.8 KJmol-¹ respectively. The standard enthalpy change (in KJ) for the reaction: CO2(g) + H2(g) --> CO(g) + H2O(g) is
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The first reaction is exothermic and the second one is endothermic. If a mixture of steam and O
2
is passed over coke and temperature is kept constant, the conversion of each to CO should not show any heat change,
i.e.,totalheatevolvedinI=totalheatabsorbedinII.
n
1
×2×110=n
2
×132
∴
n
2
n
1
=
110×2
132
=
1
0.6
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