The Law Of Multiple Proportions Was Observed For The Pair Of Two Compounds Name The Compounds
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In chemistry, the law of multiple proportions states that if two elements form more than one compound between them, then the ratios of the masses of the second element which combine with a fixed mass of the first element will always be ratios of small whole numbers.[1] This law is sometimes called Dalton's Law, named after John Dalton, the chemist who first expressed it.
For example, Dalton knew that the element carbon forms two oxides by combining with oxygen in different proportions. A fixed mass of carbon, say 100 grams, may react with 133 grams of oxygen to produce one oxide, or with 266 grams of oxygen to produce the other. The ratio of the masses of oxygen that can react with 100 grams of carbon is 266:133 = 2:1, a ratio of small whole numbers.[2] Dalton interpreted this result in his atomic theory by proposing (correctly in this case) that the two oxides have one and two oxygen atoms respectively for each carbon atom. In modern notation the first is CO (carbon monoxide) and the second is CO2 (carbon dioxide)