The limiting value of x/m is reached in the process of adsorption
(a) at low pressure,
(b) at high pressure
(c) at high temperature
(d) in vacuum
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a) at low pressure
The adsorption equation can be given as Langmuir Expression that is
x/m = ap/(1+bp)
here x is mass of gas, m is mass of adsorbent, p is pressure, a and b are Langmuir's constants
at low pressure, 1+bp will almost have 1 value so the equation can ve written as
x/m = ap which will again have very low value as p is low
Therefore, the limiting value of x/m is reached in the process of adsorption at low pressure.
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