The number of molecules of CO2 present in 44 g of CO2 is
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44 grams CO2 mean 44/44=1 mole of the CO2. 1 mole CO2 implies total of 6.022 * 10^23 molecules of CO2. 1 molecule of CO2 has 3 atoms, therefore total atoms in 44 grams of CO2 has (6.022*10^23) * 3 = 18.066 * 10^23 atoms.
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