The rate of acetolysis of trans-2-iodocyclohexyllbrosylate is much faster than the cis isomer??
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The rate constant for an isomerisation reaction of the initial concentration of a is 1 m.
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comparison to the corresponding cis isomer, the rate of solvolysis in acetic acetic is more than a million fold faster. This is because in the cis isomer, the iodo substituent cannot approach from the backside of the carbon which is undergoing substitution.
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