the rate of first order reaction is 0.04 mol /l/s at 10 seconds and 0.03 at 20 second after initiation of the reaction. the half life period of this reaction is
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U have to just put the values into the formulae for the first order eqn. that is:
K = (2.303/t2 – t1)log(Q1/Q2)
=(2.303/(10)llog(0.04/0.03)
After solving,
K = 0.02876 /min
thalf = 0.693/k = > 24 min approx
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