the resistance of 0.01 M NaCl in a conductivity cell is 210 ohms the molar conductance of this solution is 4.5 *10^3 Scm2 mol^-1 calculate cell constant of the conductivity cell
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Cell constant of the conductivity cell is found to be 9.45.
Concept:
Conductivity cells or conductivity electrodes also called as probes which are constructed from metal electrodes placed at a fixed distance in a container made-up of glass or plastic body.
The ratio of the distance between the electrodes to their surface area is termed as cell constant.
Formula:
∧m =k×1000 / m
∧m= molar conductance
k= Kappa
m= molar concentration
Given,
∧m= 4.5 *10^3 Scm2 mol^-1
m= 0.01M
R= resistance= 210 ohms
Calculation:
4.5 × 10^3 =k ×1000/ 0.01
so, k= 0.045
Calculation for cell constant:
k= cell constant/ resistance
0.045 = cell constant/ 210
Therefore, Cell constant= 0.045 × 210 = 9.45 .
Hence, Cell constant of the conductivity cell is found to be 9.45.
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