The resistance of a conductivity cell when filled with 0.02 M KCl solution is 164 ohms at 298 K. When
the cell is filled with 0.05 M AgNO3 solution its resistance is found to be 78.5 ohms at 298 K Calculate
the molar conductivity of 0.05 M AgNO3 solution if the conductivity of 0.02 M KCl solution is 2.768 x
10-3 S cm-1.
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Answer:
Resistance= Specific conductivity1×Al
Cell constant= Al=1.29cm−1
R=520ohms
Conductivity or specific conductivity= ResistanceCell constant
=5201.29=0.00248mho/cm
Molar conductivity= Molarity1000×conductivity=0.021000×0.00248=124Scm2mol−1
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