The solution of a non-volatile solute in water freezes at -0.30°C. The vapour pressure of pure water at 298 K is 23.51 mm of Hg and Kof water is 1.86 degree/molal. Calculate
the vapour pressure of this solution at 298 K.
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∆T = K×m
=> 0.3 = 1.86 × m
=> m = 0.161
m = (Xa×1000)/(1-Xa×Mb)
0.161 = (Xa×1000)/(1-Xa×18)
=> Xa = 0.00289
Also, ∆P/P° = Xa
0.00289 = (23.51 - Ps)/23.51
=> Ps = 23.442 mm
Hence, vapour pressure of this solution is: Ps = 23.442 mm of Hg
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