The van't Hoff factors for mercurous chloride and mercuric chloride are respectively unity
and greater than unity. Which of the following statements is true about two chlorides?
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Van't Hoff Value is greater than unity
Explanation:
- Van't Hoff Factor value is ratio of observed to calculated colligative property
- Van't Hoff Factor measure effect of solute on colligative property like elevation in BP, depression in FP
- Van't Hoff factor become 1 for non electrolyte solute
- Van't Hoff factor become greater than 1 if solute dissociate into particles
- It become lesser than 1 if the solute particle associate.
- →
- Mercurous Chloride gets disscociated into Hg ion and chlorine ion
- So its value of Van't Hoff factor value greater than one
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