the volume of 0.0168 mole of O2 obtained by decomposition of Kclo3 and collected by displacement of water is 428ml at a pressure of 754 mm Hg at 25 degree Celsius . The pressure of water vapour at 25 degree Celsius is
Answers
Answer:
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Given:
The volume of 0.0168 mole of O2 obtained by decomposition of Kclo3 and collected by displacement of water is 428ml at a pressure of 754 mm Hg at 25 degree Celsius .
To find:
The pressure of water vapour at 25 degree Celsius is
Solution:
From given, we have,
the volume of 0.0168 moles of O2 obtained by decomposition of Kclo3 and collected by displacement of water is 428ml at a pressure of 754 mm Hg at 25 degree Celsius.
Using the Gas law equation, we have,
n = PV/RT
n = [(753/760) × 0.428] / [0.0821 × 298] = 0.01736 mol
Now consider,
n = nw + nO2
nw = 0.01736 - 0.0168 = 0.00056 mol
The pressure of the vapour = χ{water vapour} × P
= nw/n × P
= 0.00056/0.01736 × 754
= 24.32 mm Hg
∴ The pressure of water vapour at 25 degree Celsius is 24 mm Hg