The water pressure of pure benzene at a certain temperature is 0.850 bar. A non-volatle , non-electrolyte
solid weighing 0.5g when added to 39.0 g of benzene (molar mass 78g mol-¹ ). Vapour pressure of the solution, then, 0.845 bar. What is the molar mass of the solid substance ?
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p0p0−p=W1M2W2M1
p0=0.850bar= vapour pressure of pure benzene.
p=0.845bar= vapour pressure of solution.
W1=39g= mass of benzene
W2=78g= mass of solute
M1=78g/mol= Molar mass of benzene.
M2= Molar mass of solute.
0.850bar0.850bar−0.845bar=39g×M20.5g×78g/mol
M2=170g/mol
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