Two hypothetical acids HA and HB have the dissociation constants 2 × 10⁻⁶ and 2 × 10⁻⁸ respectively in water at 25°C. Calculate the strength of HA with respect to HB.
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The dissociation constants of HA
1
and HA
2
are 3×10
−4
and 1.8×10
−5
.
The strength of an acid is directly proportional to square root of dissociation constants of acids. So relative strength of the given acids are:
(Acidic Strength)
HA
2
(Acidic Strength)
HA
1
=
(Dissociation Constant)
HA
2
(Dissociation Constant)
HA
1
Relative Acidic Strength=
(AcidicStrength)
HA
2
(AcidicStrength)
HA
1
=
1.8×10
−5
3.0×10
−4
=4.08=4(approx)
relative strengths of acids will be 4:1.
Explanation:
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