Van der waals gas equation for n number of moles is given by the formula
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To account for the volume that a real gas molecule takes up, the van der Waals equation replaces V in the ideal gas law with (V-b), where b is the volume per mole that is occupied by the molecules.
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The formula for Van der waals Force is :
[P + a(n/V) ²][V-nb]=nRT
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