what are carbo anion?? mention its types??
Answers
Question
- what are carbo anion?? mention its types??
Answer
- A carbanion is an anion in which carbon has an unshared pair of electrons and bears a negative charge usually with three substituents for a total of eight valence electrons. [1] The carbanion exists in a trigonal pyramidal geometry. Formally, a carbanion is the conjugate base of a carbon acid. R3C−H+B−→R3C−+H−B.
ANSWER ⚡
A carbanion is an anion in which carbon is trivalent (forms three bonds) and bears a formal negative charge (in at least one significant resonance form).[1]
Formally, a carbanion is the conjugate base of a carbon acid:
R3CH + :B− → R3C:− + HB
where B stands for the base. The carbanions formed from deprotonation of alkanes (at an sp3 carbon), alkenes (at an sp2 carbon), arenes (at an sp2 carbon), and alkynes (at an sp carbon) are known as alkyl, alkenyl (vinyl), aryl, and alkynyl (acetylide) anions,
respectively .Carbanions have a concentration of electron density at the negatively charged carbon, which, in most cases, reacts efficiently with a variety of electrophiles of varying strengths, including carbonyl groups, imines/iminium salts, halogenating reagents (e.g., N-bromosuccinimide and diiodine), and proton donors.
A carbanion is one of several reactive intermediates in organic chemistry. In organic synthesis, organolithium reagents and Grignard reagents are commonly treated and referred to as "carbanions." This is a convenient approximation, although these species are generally clusters or complexes containing highly polar, but still covalent bonds metal–carbon bonds (Mδ+–Cδ–) rather than true carbanions.