What concentration of nitrogen should
be present in a glass of water at room
temperature? Assume a temperature of 25°C
a total pressure of 1 atmosphere and mole
fraction of nitrogen in air of 0.78.
[Kh for nitrogen = 8.42 x 10 M/mm Hg)
(3/5, AI 2009)
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Answer:
Explanation:
PN2= 1 atmosphere
PN2=KH×N2
By Henry's law
xN2=PN2KH=18.42×10−7
xN2=n(N2)n(N2)+n(H2O)
xN2=n(N2)n(H2O)
n(N2)=xN2.n(H2O)
nN2=xN2.100018
⇒18.42×10−7×55.5
⇒6.59×107 moles
Hence concentration of nitrogen =6.59×107molL−1
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