What is anti markonikoff rule
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Anti-Markovnikov rule is also known as Kharash effect or peroxide effect. ... The anti-markovnikov rule is exactly what it sounds like - if during addition of a HX compound to an alkene, the hydrogen atom is added to the most substituted carbon atom, that is following the anti-markovnikov rule.
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Anti Markonikoff rule......
Actually it is opposite of Markonikoff rule...
It says that...
When unsymmetrical Alkene reacts with unsymmetrical reagent in the presence of peroxide then negative part of adding agent goes to that Olefins carbon atoms.... (here olefins means alkenes) which contains more number of Hydrogen atoms......
Example... CH3-CH = CH2 +HBr---- CH3-CH2-CH2-Br...in the presence of peroxide ...
Here in HBr....... hydrogen is positive and bromine is negative.... so hydrogen goes with less hydrogen atoms I. e CH and bromine goes with more hydrogen atom CH2.....
Actually it is opposite of Markonikoff rule...
It says that...
When unsymmetrical Alkene reacts with unsymmetrical reagent in the presence of peroxide then negative part of adding agent goes to that Olefins carbon atoms.... (here olefins means alkenes) which contains more number of Hydrogen atoms......
Example... CH3-CH = CH2 +HBr---- CH3-CH2-CH2-Br...in the presence of peroxide ...
Here in HBr....... hydrogen is positive and bromine is negative.... so hydrogen goes with less hydrogen atoms I. e CH and bromine goes with more hydrogen atom CH2.....
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