What is centre of gravity rules and how does it apply to the splitting of d orbital?
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A more sophisticated model to describe complexes and d-orbital splitting is the use of molecular orbital theory which comes in multiple levels (inclusion or ignorance of π-symmetric ligand orbitals). Scheme 1 shows the typical molecular orbital scheme of an octahedral complex.
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The splitting of the energy of d orbitals obeys a "center of gravity" rule.
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