Chemistry, asked by danish54, 1 year ago

what is gibbs free energy

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Answered by Anonymous
2
In thermodynamics, the Gibbs free energy (IUPAC recommended name: Gibbs energy or Gibbs function; also known as free enthalpy[1] to distinguish it from Helmholtz free energy) is a thermodynamic potential that can be used to calculate the maximum of reversible workthat may be performed by a thermodynamic system at a constant temperature and pressure(isothermal, isobaric). The Gibbs free energy(G = H-TS) (J in SI units) is the maximum amount of non-expansion work that can be extracted from a thermodynamically closed system (one that can exchange heat and work with its surroundings, but not matter); this maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces.[2]

The Gibbs energy (also referred to as G) is also the thermodynamic potential that is minimized when a system reaches chemical equilibrium at constant pressure and temperature. Its derivative with respect to the reaction coordinate of the system vanishes at the equilibrium point. As such, a reduction in G is a necessary condition for the spontaneity of processes at constant pressure and temperature.

The Gibbs free energy, originally called available energy, was developed in the 1870s by the American scientist Josiah Willard Gibbs. In 1873, Gibbs described this "available energy" as

the greatest amount of mechanical work which can be obtained from a given quantity of a certain substance in a given initial state, without increasing its total volume or allowing heat to pass to or from external bodies, except such as at the close of the processes are left in their initial condition.[3]

Answered by samimpapa354
2

Answer:

Gibbs Free energy is a quantity that is used to measure the maximum amount of work done in a thermodynamic system when the temperature and pressure are kept constant

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