Science, asked by krishpriya, 1 year ago

what is lewis concept

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Answered by Tina11111
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In the Lewis theory of acid-base reactions, bases donate pairs of electrons and acids accept pairs of electrons. A Lewis acid is therefore any substance, such as the H+ ion, that can accept a pair of nonbonding electrons. In other words, a Lewis acid is an electron-pair acceptor. A Lewis base is any substance, such as the OH- ion, that can donate a pair of nonbonding electrons. A Lewis base is therefore an electron-pair donor.

One advantage of the Lewis theory is the way it complements the model of oxidation-reduction reactions. Oxidation-reduction reactions involve a transfer of electrons from one atom to another, with a net change in the oxidation number of one or more atoms.



The Lewis theory suggests that acids react with bases to share a pair of electrons, with no change in the oxidation numbers of any atoms. Many chemical reactions can be sorted into one or the other of these classes. Either electrons are transferred from one atom to another, or the atoms come together to share a pair of electrons.

The principal advantage of the Lewis theory is the way it expands the number of acids and therefore the number of acid-base reactions. In the Lewis theory, an acid is any ion or molecule that can accept a pair of nonbonding valence electrons. In the preceding section, we concluded that Al3+ions form bonds to six water molecules to give a complex ion.

Al3+(aq) + 6 H2O(l)  Al(H2O)63+(aq)

This is an example of a Lewis acid-base reaction. The Lewis structure of water suggests that this molecule has nonbonding pairs of valence electrons and can therefore act as a Lewis base. The electron configuration of the Al3+ion suggests that this ion has empty 3s, 3p, and 3d orbitals that can be used to hold pairs of nonbonding electrons donated by neighboring water molecules.

Al3+ = [Ne] 3s0 3p0 3d0

Thus, the Al(H2O)63+ ion is formed when an Al3+ ion acting as a Lewis acid picks up six pairs of electrons from neighboring water molecules acting as Lewis bases to give an acid-base complex, or complex ion.

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