what is miscellaneous reduction
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In addition to ionic hydrogenations, dissolving metal reductions and hydrosilation reactions which we have previously considered, there are a number of reduction reactions which utilize organosilicon reagents. These have been divided into seven sections:
1) tin hydride mediated reductions,
2) reductions which utilize silyl radicals,
3) reductions with trichlorosilane (Cl3SiH)/tertiary amines,
4) reductions of phosphine oxides,
5) reductions of sulfoxides
, 6) reductions of amine oxides, and
7) reductions of α-halo ketones.
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Explanation:
In addition to ionic hydrogenations, dissolving metal reductions and hydrosilation reactions which we have previously considered, there are a number of reduction reactions which utilize organosilicon reagents.
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