What is the difference of the nominal and maximum voltage of the lithium ion battery
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Depending on the design and chemistry of your lithium cell, you may see them sold under different nominal "voltages". For example, almost all lithium polymer batteries are 3.7V or 4.2V batteries. What this means is that the maximum voltage of the cell is 4.2v and that the "nominal" (average) voltage is 3.7V. As the battery is used, the voltage will drop lower and lower until the minimum which is around 3.0V. You should see the number 3.7V written on the battery itself somewhere.
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