Chemistry, asked by komalkomal156, 1 year ago

what is the distance between Na+ and Cl- in NaCl crystal if the desity is 2.165 g /cm cube ? NaCl crystalises in FCC lattic ? At. mass of Na = 23 and Cl = 35.5 a.m.u .please reply fast.

Answers

Answered by Rico47
0
Distance between Na+andCl−=a2Na+andCl−=a2

Density ρ=2.165gcm−1ρ=2.165gcm−1

Molecular weight of NaCl = 58.5

n = 4 (Since Nacl crystallizes in fcc lattice)

We know that 2(rNa++rCl−)=a2(rNa++rCl−)=a

ρ=nMa3×N×10−30ρ=nMa3×N×10−30

Hence a3=nMρ×N×10−30a3=nMρ×N×10−30

Substituting the value we get

a3=4×58.52.165×6.023×1023×10−30a3=4×58.52.165×6.023×1023×10−30

a=[(4×58.5)2.165×6.023×1023×10−30]13a=[(4×58.5)2.165×6.023×1023×10−30]13

a = 564.17 = 564

2(rNa++rCl−)=5642(rNa++rCl−)=564

(rNa++rCl−)=282pm
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