Question

What is the effect of a magnetic field in mossbauer spectroscopy?

Answer 1

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MOSSBAUER SPECTROSCOPY...

Mössbauer spectroscopy is a spectroscopic technique based on the Mössbauer effect. This effect, discovered by Rudolf Mössbauer (also Moessbauer, German: "Mößbauer") in 1958, consists in the nearly recoil-free, resonant absorption and emission of gamma rays in solids.

Like nuclear magnetic resonance spectroscopy, Mössbauer spectroscopy probes tiny changes in the energy levels of an atomic nucleus in response to its environment. Typically, three types of nuclear interactions may be observed: isomer shift, also called chemical shift in the older literature; quadrupole splitting; and magnetic hyperfine splitting (see also the Zeeman effect). Due to the high energy and extremely narrow line widths of gamma rays, Mössbauer spectroscopy is a very sensitive technique in terms of energy (and hence frequency) resolution, capable of detecting changes in just a few parts per 10^11.

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