Question

What is the isomerism present between

[Co(N1-13)4(H20)CfiBr2and

[Co(NI-13)4Br2]C1 . H20 ?
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Answer 1

Explanation:

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Answer 2

Answer:

What is the isomerism present between

[Co(N1-13)4(H20)CfiBr2and

[Co(NI-13)4Br2]C1 . H20 ?

Explanation:

hydrate isomerism

Hydrate Isomerism : In a compound, water molecules may be present in either

coordinated form or a: ~ttice water (water of crystallisation). In the fmr case water

molecules are directly attached to the metal ion, or in the latter case they may occupy lattice

sites in a crystal bithodt getting attached to the metal ion. This type of isomerism is known

as hydrate isomerism and the physical and chemical properties of hydrate isomers are quite

different. As an example, we consider at least three well established isomers of a complex

~r~13.6~20: Theseare: /

(i) [Cr(H20)4C12] C1.2H20, a dark green compound where four molecules of water are

coordinated to Cr(II1) ion and the other two molecules occupy the lattice position..

(ii) [Cr(H20)~CI]C12.H20 is blue green in colour and has five coordinated and one

lattice molecules of water.

. A few other examples are:

[Co(NH3)4(H20)CI]Br2, [Co(NH3)4Br2]CI-H20

and [Co(NH3)3(H20)2CI]Br:. [Co(NH3)3Br2 (H2O)IBr.H20