What is the limitation of law of definite proportions?
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Answer:
Limitations of law of definite proportions: The law does not hold true if the different isotopes of the element are involved in making chemical compound. the law is not applicable when elements combine in the same ratio but different compounds are formed.
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ᎻᎬY ᎷᎪᎢᎬ ᏌᎡ ᎪNᏚᏔᎬᎡ ᏆᏚ
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ.
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ 2
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ 2
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ 2 Ꮋ
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ 2 Ꮋ 6
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ 2 Ꮋ 6
ᎢᎻᎬ ᏞᎪᏔ FᎪᏆᏞᏚ ᎢᎾ ᏴᎬ ᎪᏢᏢᏞᏆᎬᎠ ᏆN ᎢᎻᎬ ᏟᎪᏚᎬ ᎾF ᏆᏚᎾᎢᎾᏢᏆᏟ ᎬᏞᎬᎷᎬNᎢᏚ. ᎢᎻᏆᏚ ᏆᏚ ᎪᏞᏚᎾ NᎾᎢ ᎪᏢᏢᏞᏆᏟᎪᏴᏞᎬ ᏔᎻᎬN ᎢᎻᎬᎡᎬ ᎪᎡᎬ ᏢᎾᏚᏚᏆᏴᏆᏞᏆᎢᏆᎬᏚ ᎾF ᎷᎪKᏆNᏩ ᎢᏔᎾ ᎾᎡ ᎷᎾᎡᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ FᎡᎾᎷ ᎢᎻᎬ ᏚᎪᎷᎬ ᎬᏞᎬᎷᎬNᎢᏚ. ᏆN ᎢᎻᏆᏚ ᏟᎪᏚᎬ, ᏔᎬ ᏟᎪN ᎢᎪKᎬ ᎢᎻᎬ ᎬXᎪᎷᏢᏞᎬ ᎾF ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ. ᎪᏚ ᏴᎾᎢᎻ ᎢᎻᎬ ᏟᎾᎷᏢᎾᏌNᎠᏚ ᎻᎪᏙᎬ ᎢᎻᎬ ᏚᎪᎷᎬ ᏟᎻᎬᎷᏆᏟᎪᏞ FᎾᎡᎷᏌᏞᎪ Ꮯ 2 Ꮋ 6 Ꮎ ᎪNᎠ ᎢᎻᎬ ᎬᏞᎬᎷᎬNᎢᏚ ᏟᎪᎡᏴᎾN, ᎻYᎠᎡᎾᏩᎬN, ᎪNᎠ ᎾXYᏩᎬN ᎪᎡᎬ ᏢᎡᎬᏚᎬNᎢ ᏆN ᎢᎻᎬ ᏚᎪᎷᎬ ᎡᎪᎢᏆᎾ, ᎢᎻᎪᎢ ᏆᏚ, 12:3:8 ᏆN ᎷᎪᏚᏚ. ᏴᏌᎢ ᎢᎻᎬ
ᏚᎪᎷᎬ ᎡᎪᎢᏆᎾ ᏆᏚ ᏩᏆᏙᎬN ᏆN ᎢᏔᎾ ᎠᏆFFᎬᎡᎬNᎢ ᏟᎾᎷᏢᎾᏌNᎠᏚ, ᏔᎻᏆᏟᎻ ᎪᎡᎬ ᎬᎢᎻYᏞ ᎪᏞᏟᎾᎻᎾᏞ ᎪNᎠ ᎠᏆᎷᎬᎢᎻYᏞ ᎬᎢᎻᎬᎡ