Question

What is the significance of considering equilibrium states in thermodynamics

Answer 1

Overview. Classical thermodynamicsdeals with states of dynamicequilibrium. The state of a system atthermodynamic equilibrium is the one for which some thermodynamicpotential is minimized, or for which the entropy (S) is maximized, for specified conditions.

Answer 2

Then, a thermodynamic state of the system is called an equilibrium state if the thermodynamic variables characterizing the properties of the system, such as pressure, temperature, and volume, do not experience any spatial and temporal variation. The equilibrium state is also referred to as thermodynamic equilibrium.

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