What volume of M/10 and M/30 solutions of H2
SO4
should be mixed to prepare 1 L of certain H2
SO4
solution whose 50 ml is completely neutralized by 10 ml of 0.5 M NaOH solution.
Answers
Answer:
We know that H2SO4 is a dibasic acid and can release two H+ ions on hydrolysis. NaOH on the other hand is a strong base. So the reaction between a strong acid and a strong base will produce the respective salt and water. So the reaction is:
H2SO4 + 2NaOH -> Na2SO4 + 2 H2O
So, 2 mols of NaOH reacts with 1.mol of H2SO4 to give there respective salt. Therefore 25 mL of 0.1 M H2SO4 reacts with 50mL of NaOH to neutralise each other. Thus the total volume of the solution after neutralisation will be,
25+ 50= 75mL.
Now to obtain 0.05M of H2SO4 we must use some extra volume of it.
Let V1 = volume of extra H2SO4 needed = x mL
S1 = strength of the H2SO4 supplied = 0.1M
V2 = total volume of the resultant solution after adding H2SO4 = (75 + x) mL
S2 = strength of the resultant solution in H2SO4
= 0.05M
Therefore, from the principle of molarity,
V1*S1 = V2*S2
=> x * 0.1 = (75+x) * 0.05
Upon equating the value of x = 75mL.
There fore the total volume of 0.1M H2SO4 needed = 25 (for neutralisation) + 75 (for attaining concentration) = 100mL.
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