What will be the equivalent weight of as2s3 for the redox reaction?
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Answered by
8
First, I think there is a typing mistake…. it should be AsO3−4AsO43− instead of AsO−4AsO4−…….
Second, I hope you know that equivalent weight = MMNfMMNf
and
that this is a redox involving multiple oxidation ……
Also
Nf=∑(ΔOS)Nf=∑(ΔOS)
that actually means we need to add all the changes in oxidation states
NO−3+As2S3→AsO3−4+NO+SO2−4NO3−+As2S3→AsO43−+NO+SO42−
Oxidation state of As before and after the reaction is +3 and +5
and
That of S is -2 and 6
Now, NfNf = (2x2)forAs+(8x3)forS=28(2x2)forAs+(8x3)forS=28
equivalent wt of As2S3As2S3 = MM28MM28
Hope this helps.
Second, I hope you know that equivalent weight = MMNfMMNf
and
that this is a redox involving multiple oxidation ……
Also
Nf=∑(ΔOS)Nf=∑(ΔOS)
that actually means we need to add all the changes in oxidation states
NO−3+As2S3→AsO3−4+NO+SO2−4NO3−+As2S3→AsO43−+NO+SO42−
Oxidation state of As before and after the reaction is +3 and +5
and
That of S is -2 and 6
Now, NfNf = (2x2)forAs+(8x3)forS=28(2x2)forAs+(8x3)forS=28
equivalent wt of As2S3As2S3 = MM28MM28
Hope this helps.
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3
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